Tetrabromoauric acid

Tetrabromoauric acid
Names
	Other names Tetrabromoauric(III) acid; Hydrogen tetrabromoaurate(III)
Identifiers
CAS Number	17083-68-0 ;
3D model (JSmol)	Interactive image;
ChemSpider	23350057;
ECHA InfoCard	100.037.385
EC Number	241-139-9;
PubChem CID	18674916;
UNII	9LR3TA4DGO ;
CompTox Dashboard (EPA)	DTXSID601015044 DTXSID90276474, DTXSID601015044 ;
	SMILES [H+].Br[Au-](Br)(Br)Br;
Properties
Chemical formula	H[AuBr4]
Molar mass	517.591 g·mol−1
Conjugate base	Tetrabromoaurate(III)
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Tetrabromoauric acid is an inorganic compound with the formula H[AuBr₄]. It is the bromide analog of chloroauric acid. It is generated analogously, by reacting a mixture of hydrobromic and nitric acids with elemental gold.^[1]^[2] The oxidation state of gold in H[AuBr₄] and [AuBr₄]⁻ anion is +3. The salts of H[AuBr₄] (tetrabromoauric(III) acid) are tetrabromoaurates(III), containing [AuBr₄]⁻ anions (tetrabromoaurate(III) anions), which have square planar molecular geometry.

References

^ Weick, C. F.; Basolo, Fred (1966). "The Aqueous Solution Chemistry and Kinetic Behavior of a Pseudo-Octahedral Complex of Gold(III)". Inorg. Chem. 5 (4): 576. doi:10.1021/ic50038a018.
^ Afanasieva, V. A.; Glinskaya, L. A.; Klevtsova, R. F.; Mironov, I. V.; Sheludyakova, L. A. (2007). "Introduction of halogen atoms into gold(III) tetraaza metallocomplexes. Crystal and molecular structure of [Au(C₉H₁₈N₄Br)](ClO₄)₂ and [Au(C₁₄H₂₀N₄Br₂)]ClO₄". J. Struc. Chem. 48 (2): 289. Bibcode:2007JStCh..48..289A. doi:10.1007/s10947-007-0045-5. S2CID 98824031.

[1] Weick, C. F.; Basolo, Fred (1966). "The Aqueous Solution Chemistry and Kinetic Behavior of a Pseudo-Octahedral Complex of Gold(III)". Inorg. Chem. 5 (4): 576. doi:10.1021/ic50038a018.

[2] Afanasieva, V. A.; Glinskaya, L. A.; Klevtsova, R. F.; Mironov, I. V.; Sheludyakova, L. A. (2007). "Introduction of halogen atoms into gold(III) tetraaza metallocomplexes. Crystal and molecular structure of [Au(C₉H₁₈N₄Br)](ClO₄)₂ and [Au(C₁₄H₂₀N₄Br₂)]ClO₄". J. Struc. Chem. 48 (2): 289. Bibcode:2007JStCh..48..289A. doi:10.1007/s10947-007-0045-5. S2CID 98824031.

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