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Nicholas A. Kotov

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Nicholas A. Kotov
2021
Born (1965-08-29) August 29, 1965 (age 59)
Moscow, USSR
NationalityAmerican
Alma materMoscow State University
Known forself-assembling materials, layer-by-layer assembly, nanotechnology
Scientific career
FieldsChemistry, Chemical Engineering, Materials Science, Nanotechnology, Biomedical Engineering
InstitutionsUniversity of Michigan
Thesis Photoelectrochemical Effects at the Interface of the Two Immiscible Electrolyte Solutions
Doctoral advisorMikhail Kuzmin
Other academic advisorsJanos H. Fendler

Nicholas A. Kotov (born August 29, 1965, in Moscow, USSR) is the Irving Langmuir Distinguished Professor of Chemical Sciences and Engineering at the University of Michigan in Ann Arbor, MI, USA.[1] Prof. Nicholas Kotov demonstrated that the ability to self-organize into complex structures is the unifying property of all inorganic nanostructures.[2][3] He has developed a family of bioinspired composite materials with a wide spectrum of properties that were previously unattainable in classical materials.[4] These composite biomimetic materials are exemplified by his nacre-like ultrastrong yet transparent composites,[5][6] enamel-like, stiff yet vibration-isolating composites, and cartilage-like membranes with both high strength and ion conductance.[6][7][8][9]

Work

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Kotov's research is focused on the development of biomimetic nanocomposites, the self-assembly of nanoparticles,[10] and chiral nanostructures.[11] Utilizing layer-by-layer assembly (LbL),[12] Kotov prepared a wide spectrum of nacre-like nanocomposites including those from clay[13] and graphite oxide.[14] He showed that clay-based biomimetic composites can attain mechanical properties comparable to some grades of steel while retaining transparency.[15] This discovery spurred the development of new methods for the mass-production of nacre-like materials from a large variety of inorganic nanosheets.[16] While being inspired by natural materials, these composites far exceeded the properties of their natural prototypes and add other optical, electrical, thermal, and membrane properties.

Kotov extended the concept of biomimetic nanostructures to inorganic nanoparticles. He established that, similarly to many proteins and other biomolecules, nanoparticles can self-organize into chains,[10] sheets,[17] nanowires, twisted ribbons[18] and nanohelices,[19][20] and spherical supraparticles replicating viral capsids.[21]

Kotov's work established that the biomimetic self-assembly behavior of nanoparticles originates from interparticle interactions at the nanoscale,[22] in which chirality also plays a prominent role.[23] His studies on the self-assembly of chiral nanostructures have led to the development of nanoparticle assemblies with complexity exceeding those found in biological organisms.[24]

Education and research career

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Education and early career

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Kotov received his MS (1987) and PhD (1990) degrees in chemistry from Moscow State University, where his research concerned liquid-liquid interfaces imitating cell membranes for solar energy conversion. After graduation, he took up a postdoctoral position in the research group of Prof. Janos Fendler in the Department of Chemistry at Syracuse University in New York state working on nanoparticle synthesis and assembly at interfaces.

Independent research career

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Kotov took up a position as assistant professor of chemistry at the Oklahoma State University in Stillwater, Oklahoma in 1996, gaining promotion to associate professor in 2001. In 2003 he moved to the University of Michigan where he is now the Irving Langmuir Distinguished Professor of Chemical Sciences and Engineering.

Awards

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Personal life

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Kotov married chemist Elvira Stesikova, PhD, in 1991. They have two daughters, Sophia and Nicole.

References

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  1. ^ "Nicholas A. Kotov | Michigan Engineering". Engin.umich.edu. Retrieved 2013-10-08.
  2. ^ "acs.org". cen.acs.org. Retrieved 2021-02-10.
  3. ^ "Nicholas Kotov of University of Michigan is 2020 Alpha Chi Sigma Award Recipient". www.aiche.org. 2020-10-12. Retrieved 2021-02-10.
  4. ^ "Kotov wins the Stephanie L. Kwolek Award". Michigan Engineering. May 20, 2016. Retrieved 2021-02-10.
  5. ^ "U-M research: New plastic is strong as steel, transparent". EurekAlert!. Retrieved 2021-02-10.
  6. ^ a b "New Plastic is Transparent and Strong as Steel". NetComposites. Archived from the original on February 27, 2021. Retrieved 2021-02-10.{{cite web}}: CS1 maint: unfit URL (link)
  7. ^ "Membrane inspired by bone and cartilage efficiently produces electricity from saltwater". ScienceDaily. Retrieved 2021-02-10.
  8. ^ "Inspired by the Tissues of Living Organisms, Researchers Take One Step Closer to Harvesting "Blue Energy"". Yale E360. Retrieved 2021-02-10.
  9. ^ "ten15am.org".
  10. ^ a b Zhiyong Tang; Nicholas A. Kotov; Michael Giersig (2002). "Spontaneous Organization of Single CdTe Nanoparticles into Luminescent Nanowires". Science. 297 (5579): 237–40. Bibcode:2002Sci...297..237T. doi:10.1126/science.1072086. PMID 12114622. S2CID 45388619.
  11. ^ Wei Chen; Ai Bian; Ashish Agarwal; Liqiang Liu; Hebai Shen; Libing Wang; Chuanlai Xu; Nicholas A. Kotov (2009). "Nanoparticle Superstructures Made by Polymerase Chain Reaction: Collective Interactions of Nanoparticles and a New Principle for Chiral Materials". Nano Letters. 9 (5): 2153–2159. Bibcode:2009NanoL...9.2153C. doi:10.1021/nl900726s. PMID 19320495. S2CID 35163925.
  12. ^ G. Decher; J. D. Hong; J. Schmitt (1992). "Buildup of ultrathin multilayer films by a self-assembly process: III. Consecutively alternating adsorption of anionic and cationic polyelectrolytes on charged surfaces". Thin Solid Films. 210/211: 831. Bibcode:1992TSF...210..831D. doi:10.1016/0040-6090(92)90417-A.
  13. ^ Kotov, N. A.; Magonov, S.; Tropsha, E. (March 1998). "Layer-by-Layer Self-Assembly of Alumosilicate−Polyelectrolyte Composites: Mechanism of Deposition, Crack Resistance, and Perspectives for Novel Membrane Materials". Chemistry of Materials. 10 (3): 886–895. doi:10.1021/cm970649b. ISSN 0897-4756.
  14. ^ Kotov, Nicholas A.; Dékány, Imre; Fendler, Janos H. (August 1996). "Ultrathin graphite oxide-polyelectrolyte composites prepared by self-assembly: Transition between conductive and non-conductive states". Advanced Materials. 8 (8): 637–641. Bibcode:1996AdM.....8..637K. doi:10.1002/adma.19960080806.
  15. ^ Podsiadlo, Paul; Kaushik, Amit K.; Arruda, Ellen M.; Waas, Anthony M.; Shim, Bong Sup; Xu, Jiadi; Nandivada, Himabindu; Pumplin, Benjamin G.; Lahann, Joerg (2007-10-05). "Ultrastrong and Stiff Layered Polymer Nanocomposites". Science. 318 (5847): 80–83. Bibcode:2007Sci...318...80P. doi:10.1126/science.1143176. ISSN 0036-8075. PMID 17916728. S2CID 22559961.
  16. ^ Gao, Huai-Ling; Chen, Si-Ming; Mao, Li-Bo; Song, Zhao-Qiang; Yao, Hong-Bin; Cölfen, Helmut; Luo, Xi-Sheng; Zhang, Fu; Pan, Zhao (2017-08-18). "Mass production of bulk artificial nacre with excellent mechanical properties". Nature Communications. 8 (1): 287. Bibcode:2017NatCo...8..287G. doi:10.1038/s41467-017-00392-z. ISSN 2041-1723. PMC 5562756. PMID 28821851.
  17. ^ Zhiyong Tang; Zhenli Zhang; Ying Wang; Sharon C. Glotzer; Nicholas A. Kotov (2006). "Self-Assembly of CdTe Nanocrystals into Free-Floating Sheets". Science. 314 (5797): 274–8. Bibcode:2006Sci...314..274T. doi:10.1126/science.1128045. PMID 17038616. S2CID 18839769.
  18. ^ Sudhanshu Srivastava; Aaron Santos; Kevin Critchley; Ki-Sub Kim; Paul Podsiadlo; Kai Sun; Jaebeom Lee; Chuanlai Xu; G. Daniel Lilly; Sharon C. Glotzer; Nicholas A. Kotov (2010). "Light-Controlled Self-Assembly of Semiconductor Nanoparticles into Twisted Ribbons". Science. 327 (5971): 1355–9. Bibcode:2010Sci...327.1355S. doi:10.1126/science.1177218. PMID 20150443. S2CID 22492581.
  19. ^ Zhou, Yunlong; Marson, Ryan L.; van Anders, Greg; Zhu, Jian; Ma, Guanxiang; Ercius, Peter; Sun, Kai; Yeom, Bongjun; Glotzer, Sharon C. (2016-03-22). "Biomimetic Hierarchical Assembly of Helical Supraparticles from Chiral Nanoparticles". ACS Nano. 10 (3): 3248–3256. doi:10.1021/acsnano.5b05983. ISSN 1936-0851. OSTI 1440921. PMID 26900920. S2CID 30561840.
  20. ^ Feng, Wenchun; Kim, Ji-Young; Wang, Xinzhi; Calcaterra, Heather A.; Qu, Zhibei; Meshi, Louisa; Kotov, Nicholas A. (2017-03-01). "Assembly of mesoscale helices with near-unity enantiomeric excess and light-matter interactions for chiral semiconductors". Science Advances. 3 (3): e1601159. Bibcode:2017SciA....3E1159F. doi:10.1126/sciadv.1601159. ISSN 2375-2548. PMC 5332156. PMID 28275728.
  21. ^ Xia, Yunsheng; Nguyen, Trung Dac; Yang, Ming; Lee, Byeongdu; Santos, Aaron; Podsiadlo, Paul; Tang, Zhiyong; Glotzer, Sharon C.; Kotov, Nicholas A. (2011-08-21). "Self-assembly of self-limiting monodisperse supraparticles from polydisperse nanoparticles". Nature Nanotechnology. 6 (9): 580–587. Bibcode:2011NatNa...6..580X. doi:10.1038/nnano.2011.121. ISSN 1748-3395. PMID 21857686.
  22. ^ Batista, Carlos A. Silvera; Larson, Ronald G.; Kotov, Nicholas A. (2015-10-09). "Nonadditivity of nanoparticle interactions". Science. 350 (6257): 1242477. doi:10.1126/science.1242477. ISSN 0036-8075. PMID 26450215.
  23. ^ Ma, Wei; Xu, Liguang; de Moura, André F.; Wu, Xiaoling; Kuang, Hua; Xu, Chuanlai; Kotov, Nicholas A. (2017-06-28). "Chiral Inorganic Nanostructures". Chemical Reviews. 117 (12): 8041–8093. doi:10.1021/acs.chemrev.6b00755. ISSN 0009-2665. PMID 28426196.
  24. ^ Jiang, Wenfeng; Qu, Zhi-bei; Kumar, Prashant; Vecchio, Drew; Wang, Yuefei; Ma, Yu; Bahng, Joong Hwan; Bernardino, Kalil; Gomes, Weverson R.; Colombari, Felippe M.; Lozada-Blanco, Asdrubal (2020-05-08). "Emergence of complexity in hierarchically organized chiral particles". Science. 368 (6491): 642–648. Bibcode:2020Sci...368..642J. doi:10.1126/science.aaz7949. ISSN 0036-8075. PMID 32273399. S2CID 215726726.
  25. ^ David Turnbull Lectureship Recipients
  26. ^ Nanoscale Science and Engineering Forum Award
  27. ^ 2020 National Academy of Inventors
  28. ^ 2020 Alpha Chi Sigma Award Recipient
  29. ^ Recipients Newton Award
  30. ^ Faculty Profile
  31. ^ 2018 Vannevar Bush Fellows
  32. ^ Soft Matter and Biophysical Chemistry Award Winners
  33. ^ a b Humboldt Foundation Fellowships
  34. ^ 2017 Colloid Chemistry Award Recipients
  35. ^ 2016 Kwolek Award Recipients
  36. ^ Fifth UNESCO Medals
  37. ^ 2014 Materials Research Society Medal Recipients
  38. ^ Fellow of the Materials Research Society
  39. ^ 2012 Stine Award for Materials Research
  40. ^ Top 100 Materials Scientists in 2000-2010
  41. ^ Top 100 Chemists in 2000-2010
  42. ^ 2008 Top 10 Discoveries of the Year
  43. ^ Gran Prix, Materials Research Society Entrepreneurship Challenge
  44. ^ NSF Career Award
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