Ammonium ozonide
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| Identifiers | |
|---|---|
3D model (JSmol)
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| Properties | |
| H4NO3 | |
| Molar mass | 66.036 g·mol−1 |
| Appearance | Deep red solid |
| Related compounds | |
Other anions
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Ammonium nitrate |
Other cations
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Potassium ozonide, Caesium ozonide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Ammonium ozonide is an oxygen rich molecule containing an ammonium cation (NH4+) and an ozonide anion (O3−). Ammonium ozonide, like alkali ozonides, is a red solid.[1][2] Ammonium ozonide is stable at low temperatures, but it decomposes to ammonium nitrate at temperatures above -70 °C.[2]
Preparation and decomposition
[edit]Ammonium ozonide is made by bubbling gaseous ozone through liquid ammonia at -110 °C.[1][2] This method suffers from a low yield.[1]
- 12 NH3 + 11 O3 → 9 NH4O3 + 3 NO2
Ammonium ozonide decomposes into ammonium nitrate, oxygen gas, and water. If the above reaction is done at high temperatures, these decomposition products result immediately and no ozonide is formed.[1]
- 4 NH4O3 → 2 NH4NO3 + O2 + 4 H2O
References
[edit]- ^ a b c d Solomon, Irvine J.; Hattori, Kiyo.; Kacmarek, Andrew J.; Platz, Gerald M.; Klein, Morton J. (January 1962). "Ammonium Ozonide". Journal of the American Chemical Society. 84 (1): 34–36. doi:10.1021/ja00860a008. ISSN 0002-7863.
- ^ a b c McGee, Henry (July 1966). Chemical Reactivity of Hydrogen, Nitrogen, and Oxygen Atoms at Temperatures below 100° K (PDF). NASA (Report). pp. 1–98. A-661.
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